排序方式: 共有83条查询结果,搜索用时 109 毫秒
21.
Ghasemzadeh Nasim Iranbakhsh Alireza Oraghi-Ardebili Zahra Saadatmand Sara Jahanbakhsh-Godehkahriz Sodabeh 《Environmental science and pollution research international》2022,29(24):35897-35907
Environmental Science and Pollution Research - Cold plasma (CP) application has increasing interest due to its environmental-friendly, high efficient, and low cost aspects to mitigate deletion... 相似文献
22.
Dadashi Zahra Mahmoudi Ali Rashidi Saman 《Environmental science and pollution research international》2022,29(32):47837-47866
Environmental Science and Pollution Research - Slowing and reversing climate change and keeping energy prices at affordable levels are the main important achievements of the use of renewable... 相似文献
23.
Mahmodi Sheikh Sarmast Zahra Sedaghat Sajjad Derakhshi Pirouz Azar Parviz Aberoomand 《Journal of Polymers and the Environment》2022,30(7):2990-3004
Journal of Polymers and the Environment - In this study, Fe3O4 nanoparticles and chitosan along with silver nanoparticles was synthesized to apply for the rapid and simple removal of amoxicillin... 相似文献
24.
A new strategy for determination of hydroxylamine and phenol in water and waste water samples using modified nanosensor 总被引:2,自引:0,他引:2
Roya Sadeghi Hassan Karimi-Maleh Mohammad A. Khalilzadeh Hadi Beitollahi Zahra Ranjbarha Mohammad Bagher Pasha Zanousi 《Environmental science and pollution research international》2013,20(9):6584-6593
A carbon paste electrode modified with p-chloranil and carbon nanotubes was used for the sensitive and selective voltammetric determination of hydroxylamine (HX) and phenol (PL). The oxidation of HX at the modified electrode was investigated by cyclic voltammetry (CV), chronoamperommetry, and electrochemical impedance spectroscopy. The values of the catalytic rate constant (k), and diffusion coefficient (D) for HX were calculated. Square wave voltammetric peaks current of HX and PL increased linearly with their concentrations at the ranges of 0.1–172.0 and 5.0–512.0 μmol L?1, respectively. The detection limits for HX and PL were 0.08 and 2.0 μmol L?1, respectively. The separation of the anodic peak potentials of HX and PL reached to 0.65 V, using square wave voltammetry. The proposed sensor was successfully applied for the determination of HX and PL in water and wastewater samples. 相似文献
25.
Fatemeh Sabermahani Zahra Hassani Mahboobeh Faramarzpoor 《Environmental monitoring and assessment》2013,185(6):4969-4976
The aim of the present work is the assessment of a new sorbent, prepared using silica gel coated with a pyrimidine derivative (allyl 6-methyl-4-phenyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate), for extraction and preconcentration trace amount of lead from different samples prior to determination by flame atomic absorption spectrometry. Common coexisting ions did not interfere with the separation and determination of lead at pH?6, so that lead ion completely adsorbed on the column. The limit of detection based on three times the standard deviation of the blank was found to be 0.53 ng?mL?1 in original solution. Obtained sorption capacity for 1 g sorbent was 5.0 mg Pb. The linearity was maintained in the concentration range of 0.1–30.0 ng?mL?1 for the concentrated solution. Eight replicate determinations of 2.0 μg?mL?1 of lead in the final solution gave relative standard deviation of ±2.6 %. The proposed method was successfully applied to the determination trace amounts of lead in the environmental samples such as carrot, rice, zardchoobe, and real water samples. 相似文献
26.
27.
A simple and rapid ligand-less in situ surfactant-based solid phase extraction method for preconcentration of silver from water samples is developed. In this method, a cationic surfactant containing a proper alkyl group (n-dodecyltrimethylammonium bromide) is dissolved in the aqueous sample and then a proper ion-pairing agent (ClO4?) is added. Due to the interaction between surfactant and ion-pairing agent, solid particles are formed and used for adsorption of silver carbonate. After centrifugation, the sediment is dissolved in 2.0 mL 1 M HNO3 in ethanol and then aspirated directly into the flame atomic absorption spectrometer. Variables affecting the extraction efficiencies such as pH, concentrations of surfactant and CO32?, ion pair concentration, and extraction time, are optimized. Under such conditions, the calibration curve is linear from 3 to 700 μg L?1. Detection limit is 1.1 μg L?1 with an enrichment factor of 37. The relative standard deviation for eight replicate measurements of 100 μg L?1 is 2.1%. The method has been applied for the determination of silver in water samples. 相似文献
28.
Zahra Arabi Mehdi Homaee Mohammad Esmaeil Asadi Safoora Asadi Kapourchal 《Chemistry and Ecology》2017,33(5):389-402
The influence of a natural (citric acid) and two synthetic chelates (HEDTA, EGTA) on Cd phytoextraction with radish was studied. The experiment was conducted with Cd treatments including 0 (control), 5, 20, 60 and 100?mg?Cd?kg?1 soil. When plants were fully developed, the designated HEDTA, EGTA and citric acid were applied to establish experimental treatments. Ten days after chelate applications, soil and plant samples were taken. Results indicated that synthetic chelates can considerably increase Cd concentration in soil solution compared with citric acid. Among the applied chelates, HEDTA provided more significant influences on soil solution. Cadmium concentration in both shoots and roots of radish was increased due to enhancing influence of chelate applications on Cd concentration in soil solution. Cadmium concentration in radish shoots was more than that of roots. This can be attributed to higher bioavailability and solubility of Cd in soil solution. In all treatments which received HEDTA, the cadmium concentration in both shoots and roots of radish was increased more than that of other applied chelates. Although HEDTA is more efficient in phytoextracting Cd than other chelates, due to durability of synthetic chelates toxic effects on soils, we recommend using larger amounts of light acids. 相似文献
29.
Burkhard Wilske Mo Bai Beate Lindenstruth Martin Bach Zahra Rezaie Hans-Georg Frede Lutz Breuer 《Environmental science and pollution research international》2014,21(16):9453-9460
Superabsorbent polymers (SAP) are used, inter alia, as soil amendment to increase the water holding capacity of soils. Biodegradability of soil conditioners has become a desired key characteristic to protect soil and groundwater resources. The present study characterized the biodegradability of one acrylate based SAP in four agricultural soils and at three temperatures. Mineralisation was measured as the 13CO2 efflux from 13C-labelled SAP in soil incubations. The SAP was either single-labelled in the carboxyl C-atom or triple-labelled including additionally the two C-atoms interlinked in the SAP backbone. The dual labelling allowed estimating the degradation of the polyacrylate main chain. The 13CO2 efflux from samples was measured using an automated system including wavelength-scanned cavity ring-down spectroscopy. Based on single-labelled SAP, the mean degradation after 24 weeks varied between 0.45 % in loamy sand and 0.82 % in loam. However, the differences between degradation rates in different soils were not significant due to a large intra-replicate variability. Similarly, mean degradation did not differ significantly between effective temperature regimes of 20° and 30 °C after 12 weeks. Results from the triple-labelled SAP were lower as compared to their single-labelled variant. Detailed results suggest that the polyacrylate main chain degraded in the soils, if at all, at rates of 0.12–0.24 % per 6 months. 相似文献
30.
Hassan Taghipour Zahra Amjad Mohamad Asghari Jafarabadi Akbar Gholampour Parviz Nowrouz 《Waste management (New York, N.Y.)》2014,34(7):1251-1256
From environmental viewpoint, the most important advantage of compact fluorescent lamps (CFLs) is reduction of green house gas emissions. But their significant disadvantage is disposal of spent lamps because of containing a few milligrams of toxic metals, especially mercury and lead. For a successful implementation of any waste management plan, availability of sufficient and accurate information on quantities and compositions of the generated waste and current management conditions is a fundamental prerequisite. In this study, CFLs were selected among 20 different brands in Iran. Content of heavy metals including mercury, lead, nickel, arsenic and chromium was determined by inductive coupled plasma (ICP). Two cities, Tehran and Tabriz, were selected for assessing the current waste management condition of CFLs. The study found that waste generation amount of CFLs in the country was about 159.80, 183.82 and 153.75 million per year in 2010, 2011 and 2012, respectively. Waste generation rate of CFLs in Iran was determined to be 2.05 per person in 2012. The average amount of mercury, lead, nickel, arsenic and chromium was 0.417, 2.33, 0.064, 0.056 and 0.012 mg per lamp, respectively. Currently, waste of CFLs is disposed by municipal waste stream in waste landfills. For improving the current conditions, we propose by considering the successful experience of extended producer responsibility (EPR) in other electronic waste management. The EPR program with advanced recycling fee (ARF) is implemented for collecting and then recycling CFLs. For encouraging consumers to take the spent CFLs back at the end of the products’ useful life, a proportion of ARF (for example, 50%) can be refunded. On the other hand, the government and Environmental Protection Agency should support and encourage recycling companies of CFLs both technically and financially in the first place. 相似文献